Instantaneous Hydrolysis of Nerve‐Agent Simulants with a Six‐Connected Zirconium‐Based Metal–Organic Framework | Zendy

Moon SuYoung | Zendy; Liu Yangyang | Zendy; Hupp Joseph T. | Zendy; Farha Omar K. | Zendy

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Instantaneous Hydrolysis of Nerve‐Agent Simulants with a Six‐Connected Zirconium‐Based Metal–Organic Framework

Author(s) -

Moon SuYoung,

Liu Yangyang,

Hupp Joseph T.,

Farha Omar K.

Publication year - 2015

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201502155

Subject(s) - hydrolysis , zirconium , reusability , metal organic framework , filtration (mathematics) , chemical engineering , catalysis , chemistry , materials science , inorganic chemistry , organic chemistry , computer science , adsorption , statistics , mathematics , software , engineering , programming language

A nerve‐agent simulant based on a phosphate ester is hydrolyzed using a MOF‐based catalyst. Suspensions of MOF‐808 (6‐connected), a material featuring 6‐connected zirconium nodes, display the highest hydrolysis rates among all MOFs that have been reported to date. A plug‐flow reactor was also prepared with MOF‐808 (6‐connected) as the active layer. Deployed in a simple filtration scheme, the reactor displayed high hydrolysis efficiency and reusability.

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