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Palladium‐Catalyzed Hydrocarboxylation of Alkynes with Formic Acid
Author(s) -
Hou Jing,
Xie JianHua,
Zhou QiLin
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201501054
Subject(s) - formic acid , palladium , chemistry , regioselectivity , catalysis , acrylic acid , organic chemistry , copolymer , polymer
A palladium‐catalyzed hydrocarboxylation of alkynes with formic acid has been developed. The method provides acrylic acid and derivatives in good yields with high regioselectivity without the need to handle toxic CO gas.