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Phenanthriporphyrin: An Antiaromatic Aceneporphyrinoid as a Ligand for a Hypervalent Organophosphorus(V) Moiety
Author(s) -
Szyszko Bartosz,
Białońska Agata,
Szterenberg Ludmiła,
LatosGrażyński Lechosław
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201500732
Subject(s) - hypervalent molecule , antiaromaticity , moiety , chemistry , phenanthrene , ligand (biochemistry) , derivative (finance) , porphyrin , stereochemistry , aromaticity , molecule , organic chemistry , receptor , biochemistry , reagent , financial economics , economics
The incorporation of a phenanthrene moiety into a porphyrin framework results in the formation of a hybrid macrocycle—phenanthriporphyrin—merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative.