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Frontispiz: Heterolytic Cleavage of Hydrogen by an Iron Hydrogenase Model: An Fe‐H⋅⋅⋅H‐N Dihydrogen Bond Characterized by Neutron Diffraction
Author(s) -
Liu Tianbiao,
Wang Xiaoping,
Hoffmann Christina,
DuBois Daniel L.,
Bullock R. Morris
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201482171
Subject(s) - heterolysis , neutron diffraction , crystallography , chemistry , cleavage (geology) , hydrogen , hydrogenase , hydrogen bond , materials science , crystal structure , molecule , catalysis , organic chemistry , fracture (geology) , composite material
R. M. Bullock et al. nutzen in der Zuschrift auf S. 5404 ff. einen synthetischen Modellkomplex einer Eisenhydrogenase, um mittels Neutronenbeugung die heterolytische Spaltung von H 2 zu untersuchen.