Enhanced Luminescent Properties of an Open‐Shell (3,5‐Dichloro‐4‐pyridyl)bis(2,4,6‐trichlorophenyl)methyl Radical by Coordination to Gold | Zendy

Hattori Yohei | Zendy; Kusamoto Tetsuro | Zendy; Nishihara Hiroshi | Zendy

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Enhanced Luminescent Properties of an Open‐Shell (3,5‐Dichloro‐4‐pyridyl)bis(2,4,6‐trichlorophenyl)methyl Radical by Coordination to Gold

Author(s) -

Hattori Yohei,

Kusamoto Tetsuro,

Nishihara Hiroshi

Publication year - 2015

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201411572

Subject(s) - quantum yield , luminescence , photochemistry , fluorescence , chemistry , photoluminescence , open shell , ligand (biochemistry) , materials science , organic chemistry , receptor , biochemistry , physics , optoelectronics , quantum mechanics

A gold(I) complex containing an open‐shell luminescent (3,5‐dichloro‐4‐pyridyl)bis(2,4,6‐trichlorophenyl)methyl (PyBTM) radical was prepared. The complex showed fluorescence centered mainly on the coordinated PyBTM ligand. The photophysical and photochemical properties were positively modulated upon coordination to Au I ; the photoluminescence quantum yield, fluorescence wavelength, and the stability in the photoexcited state all increased.

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