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Synthesis and Characterization of Fluorodinitroamine, FN(NO 2 ) 2
Author(s) -
Christe Karl O.,
Wilson William W.,
BélangerChabot Guillaume,
Haiges Ralf,
Boatz Jerry A.,
Rahm Martin,
Prakash G. K. Surya,
Saal Thomas,
Hopfinger Mathias
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201410507
Subject(s) - raman spectroscopy , characterization (materials science) , chemistry , nuclear magnetic resonance spectroscopy , ion , spectroscopy , inorganic chemistry , crystallography , stereochemistry , materials science , nanotechnology , organic chemistry , physics , quantum mechanics , optics
NF 3 and N(NO 2 ) 3 are known compounds, whereas the mixed fluoronitroamines, FN(NO 2 ) 2 and F 2 NNO 2 , have been unknown thus far. One of these, FN(NO 2 ) 2 , has now been prepared and characterized by multinuclear NMR and Raman spectroscopy. FN(NO 2 ) 2 is the first known example of an inorganic fluoronitroamine. It is a thermally unstable, highly energetic material formed by the fluorination of the dinitramide anion using NF 4 + salts as the preferred fluorinating agent.