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A Highly Selective Copper–Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO 2 to CO
Author(s) -
Rasul Shahid,
Anjum Dalaver H.,
Jedidi Abdesslem,
Minenkov Yury,
Cavallo Luigi,
Takanabe Kazuhiro
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201410233
Subject(s) - electrocatalyst , overpotential , electrochemistry , bimetallic strip , inorganic chemistry , aqueous solution , noble metal , copper , chemistry , indium , alloy , electrochemical reduction of carbon dioxide , materials science , metal , chemical engineering , catalysis , electrode , carbon monoxide , organic chemistry , engineering
The challenge in the electrochemical reduction of aqueous carbon dioxide is in designing a highly selective, energy‐efficient, and non‐precious‐metal electrocatalyst that minimizes the competitive reduction of proton to form hydrogen during aqueous CO 2 conversion. A non‐noble metal electrocatalyst based on a copper‐indium (Cu‐In) alloy that selectively converts CO 2 to CO with a low overpotential is reported. The electrochemical deposition of In on rough Cu surfaces led to Cu‐In alloy surfaces. DFT calculations showed that the In preferentially located on the edge sites rather than on the corner or flat sites and that the d‐electron nature of Cu remained almost intact, but adsorption properties of neighboring Cu was perturbed by the presence of In. This preparation of non‐noble metal alloy electrodes for the reduction of CO 2 provides guidelines for further improving electrocatalysis.