A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores | Zendy

Feng Dawei | Zendy; Wang Kecheng | Zendy; Su Jie | Zendy; Liu TianFu | Zendy; Park Jihye | Zendy; Wei Zhangwen | Zendy; Bosch Mathieu | Zendy; Yakovenko Andrey | Zendy; Zou Xiaodong | Zendy; Zhou HongCai | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Highly Stable Zeotype Mesoporous Zirconium Metal–Organic Framework with Ultralarge Pores

Author(s) -

Feng Dawei,

Wang Kecheng,

Su Jie,

Liu TianFu,

Park Jihye,

Wei Zhangwen,

Bosch Mathieu,

Yakovenko Andrey,

Zou Xiaodong,

Zhou HongCai

Publication year - 2015

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201409334

Subject(s) - mesoporous material , metal organic framework , zirconium , materials science , chemical engineering , aqueous solution , metal , surface modification , nanotechnology , chemistry , inorganic chemistry , organic chemistry , adsorption , catalysis , metallurgy , engineering

Through topological rationalization, a zeotype mesoporous Zr‐containing metal–organic framework (MOF), namely PCN‐777, has been designed and synthesized. PCN‐777 exhibits the largest cage size of 3.8 nm and the highest pore volume of 2.8 cm 3 g −1 among reported Zr‐MOFs. Moreover, PCN‐777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN‐777 and different guests can be varied to realize efficient immobilization.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research