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Synthesis of Aryldiazoacetates through Palladium(0)‐Catalyzed Deacylative Cross‐Coupling of Aryl Iodides with Acyldiazoacetates
Author(s) -
Ye Fei,
Wang Chengpeng,
Zhang Yan,
Wang Jianbo
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201407653
Subject(s) - aryl , palladium , catalysis , coupling reaction , chemistry , acceptor , coupling (piping) , combinatorial chemistry , photochemistry , organic chemistry , materials science , alkyl , physics , metallurgy , condensed matter physics
Palladium(0)‐catalyzed deacylative cross‐coupling of aryl iodides and acyldiazocarbonyl compounds can be achieved at room temperature under mild reaction conditions. The coupling reaction represents a highly efficient and general method for the synthesis of aryldiazocarbonyl compounds, which have found wide and increasing applications as precursors for generating donor/acceptor‐substituted metallocarbenes.