A  cis ‐Divacant Octahedral and Mononuclear Iron(IV) Imide | Zendy

Searles Keith | Zendy; Fortier Skye | Zendy; Khusniyarov Marat M. | Zendy; Carroll Patrick J. | Zendy; Sutter Jörg | Zendy; Meyer Karsten | Zendy; Mindiola Daniel J. | Zendy; Caulton Kenneth G. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A cis ‐Divacant Octahedral and Mononuclear Iron(IV) Imide

Author(s) -

Searles Keith,

Fortier Skye,

Khusniyarov Marat M.,

Carroll Patrick J.,

Sutter Jörg,

Meyer Karsten,

Mindiola Daniel J.,

Caulton Kenneth G.

Publication year - 2014

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201407156

Subject(s) - octahedron , imide , pyridine , chemistry , electron paramagnetic resonance , redox , ligand (biochemistry) , medicinal chemistry , crystallography , inorganic chemistry , polymer chemistry , crystal structure , nuclear magnetic resonance , physics , biochemistry , receptor

A rare, low‐spin Fe IV imide complex [(pyrr 2 py)FeNAd] (pyrr 2 py 2− =bis(pyrrolyl)pyridine; Ad=1‐adamantyl) confined to a cis‐divacant octahedral geometry, was prepared by reduction of N 3 Ad by the Fe II precursor [(pyrr 2 py)Fe(OEt 2 )]. The imide complex is low‐spin with temperature‐independent paramagnetism. In comparison to an authentic Fe III complex, such as [(pyrr 2 py)FeCl], the pyrr 2 py 2− ligand is virtually redox innocent.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research