Electron‐Transfer Photochromism To Switch Bulk Second‐Order Nonlinear Optical Properties with High Contrast | Zendy

Li PeiXin | Zendy; Wang MingSheng | Zendy; Zhang MingJian | Zendy; Lin ChenSheng | Zendy; Cai LiZhen | Zendy; Guo ShengPing | Zendy; Guo GuoCong | Zendy

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Electron‐Transfer Photochromism To Switch Bulk Second‐Order Nonlinear Optical Properties with High Contrast

Author(s) -

Li PeiXin,

Wang MingSheng,

Zhang MingJian,

Lin ChenSheng,

Cai LiZhen,

Guo ShengPing,

Guo GuoCong

Publication year - 2014

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201406554

Subject(s) - photochromism , viologen , electron transfer , photochemistry , chemistry , nonlinear optical , nonlinear optics , ligand (biochemistry) , photoinduced electron transfer , electron , nonlinear system , zinc , materials science , physics , organic chemistry , biochemistry , receptor , quantum mechanics

The first bulk electron‐transfer photochromic compound with intrinsic second‐order nonlinear optical (NLO) photoswitching properties has been synthesized. This system employs an electron‐transfer photoactive asymmetric viologen ligand coordinated to a zinc(II) center.

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