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Sequential Logic Operations with a Molecular Keypad Lock with Four Inputs and Dual Fluorescence Outputs
Author(s) -
Jiang XiongJie,
Ng Dennis K. P.
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201406002
Subject(s) - keypad , fluorescence , conjugate , rhodamine , combinatorial chemistry , chemistry , metal ions in aqueous solution , dual (grammatical number) , lock (firearm) , photochemistry , computer science , metal , materials science , computer hardware , mathematics , organic chemistry , physics , engineering , mechanical engineering , art , mathematical analysis , literature , quantum mechanics
A novel coumarin–rhodamine conjugate was prepared, and its metal binding properties were studied by UV/Vis and fluorescence spectroscopy. The conjugate serves as a ratiometric and highly selective fluorescent sensor for Hg 2+ ions. Its metal‐responsive spectral properties were utilized to construct a molecular keypad lock with four inputs and dual fluorescence outputs. The complexity of this molecular logic network can greatly enhance the security level of this device.

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