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Accessing the Single‐Electron Manifold: Magnesium‐mediated Hydrogen Release from Silanes
Author(s) -
Liptrot David J.,
Hill Professor Michael S.,
Mahon Mary F.
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201403208
Subject(s) - silanes , chemistry , hydride , metathesis , magnesium , hydrogen , catalysis , redox , photochemistry , combinatorial chemistry , inorganic chemistry , organic chemistry , silane , polymerization , polymer
Reactions of TEMPO (2,2,6,6‐tetramethyl‐1‐piperidinyloxy) with magnesium hydride species initiate oxidative hydrogen release, which may be elaborated to a catalytic regime within a manifold constructed about sequential TEMPO‐mediated redox and MgO/SiH metathesis processes.
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