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Multifunctional Redox Polymers: Electrochrome, Polyelectrolyte, Sensor, Electrode Modifier, Nanoparticle Stabilizer, and Catalyst Template
Author(s) -
Deraedt Christophe,
Rapakousiou Amalia,
Wang Yanlan,
Salmon Lionel,
Bousquet Melanie,
Astruc Didier
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201403062
Subject(s) - polyelectrolyte , nanoparticle , ethylene glycol , biocompatibility , redox , materials science , catalysis , stabilizer (aeronautics) , polymer , click chemistry , valency , nanotechnology , polymer chemistry , chemical engineering , chemistry , organic chemistry , mechanical engineering , linguistics , philosophy , engineering , metallurgy , composite material
Simple “click” polycondensation metallopolymers of redox‐robust bis(ethynyl)biferrocene (biFc) and di(azido) poly(ethylene glycol) (PEG400 and PEG1000) were designed for multiple functions including improvement of water solubility and biocompatibility, the introduction of mixed valency and sensing capabilities, and as nanoparticle stabilizers for catalysis.