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Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal–Organic Framework Thin Film
Author(s) -
Lu Chunjing,
Ben Teng,
Xu Shixian,
Qiu Shilun
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201402950
Subject(s) - microporous material , polyaniline , materials science , porosity , conductive polymer , electrochemistry , chemical engineering , thin film , electrical conductor , polymer , substrate (aquarium) , polyaniline nanofibers , nanotechnology , metal organic framework , polymer chemistry , electrode , composite material , adsorption , chemistry , organic chemistry , polymerization , oceanography , geology , engineering
A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well‐defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m 2 g −1 and a high electric conductivity of 0.125 S cm −1 when doped with I 2 , which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.