Selective Reductive Coupling of Nitro Compounds with Aldehydes to Nitrones in H 2  Using Carbon‐Supported and ‐Decorated Platinum Nanoparticles | Zendy

Cisneros Larisha | Zendy; Serna Pedro | Zendy; Corma Avelino | Zendy

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Selective Reductive Coupling of Nitro Compounds with Aldehydes to Nitrones in H 2 Using Carbon‐Supported and ‐Decorated Platinum Nanoparticles

Author(s) -

Cisneros Larisha,

Serna Pedro,

Corma Avelino

Publication year - 2014

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201402878

Subject(s) - nitro , catalysis , nitrone , platinum , platinum nanoparticles , selectivity , chemistry , carbon fibers , nanoparticle , coupling reaction , metal , combinatorial chemistry , inorganic chemistry , organic chemistry , nanotechnology , materials science , cycloaddition , alkyl , composite number , composite material

Nitrones were synthesized in high yields directly from nitro compounds, aldehydes, and H 2 using carbon‐decorated platinum nanoparticles. The high selectivity for nitrone synthesis contrasts that of common supported metal catalysts and corresponds to an increase from roughly 6 to 97 %. The catalytic performance is tuned by precise control of the structure of the active sites and the characteristics of the support.

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