Iridium‐Catalyzed Enantioselective CH Alkylation of Ferrocenes with Alkenes Using Chiral Diene Ligands | Zendy

Shibata Takanori | Zendy; Shizuno Tsubasa | Zendy

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Iridium‐Catalyzed Enantioselective CH Alkylation of Ferrocenes with Alkenes Using Chiral Diene Ligands

Author(s) -

Shibata Takanori,

Shizuno Tsubasa

Publication year - 2014

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201402518

Subject(s) - enantioselective synthesis , diene , alkylation , chemistry , cationic polymerization , regioselectivity , iridium , moiety , ferrocene , catalysis , ligand (biochemistry) , stereochemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , receptor , biochemistry , natural rubber , electrode , electrochemistry

The first catalytic and enantioselective CH alkylation of ferrocene derivatives with various alkenes was achieved. A cationic iridium complex, having a chiral diene ligand, and an isoquinolyl moiety as a directing group are essential for regioselective and enantioselective CH bond activation.

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