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Responsive Supramolecular Polymers Based on the Bis[alkynylplatinum(II)] Terpyridine Molecular Tweezer/Arene Recognition Motif
Author(s) -
Tian YuKui,
Shi YongGang,
Yang ZhiShuai,
Wang Feng
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201402192
Subject(s) - terpyridine , supramolecular chemistry , anthracene , molecular recognition , pyrene , supramolecular polymers , polymerization , chemistry , polymer chemistry , polymer , photochemistry , molecule , organic chemistry , metal
Supramolecular polymers are constructed based on the novel bis[alkynylplatinum(II)] terpyridine molecular tweezer/pyrene recognition motif. Successive addition of anthracene as the diene and cyano‐functionalized dienophile triggers the reversible supramolecular polymerization process, thus advancing the concept of utilizing Diels–Alder chemistry to access stimuli‐responsive materials in compartmentalized systems.