Aza[6]helicene Platinum Complexes: Chirality Control of  cis–trans  Isomerism | Zendy

Mendola Daniele | Zendy; Saleh Nidal | Zendy; Vanthuyne Nicolas | Zendy; Roussel Christian | Zendy; Toupet Loïc | Zendy; Castiglione Franca | Zendy; Caronna Tullio | Zendy; Mele Andrea | Zendy; Crassous Jeanne | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Aza[6]helicene Platinum Complexes: Chirality Control of cis–trans Isomerism

Author(s) -

Mendola Daniele,

Saleh Nidal,

Vanthuyne Nicolas,

Roussel Christian,

Toupet Loïc,

Castiglione Franca,

Caronna Tullio,

Mele Andrea,

Crassous Jeanne

Publication year - 2014

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201401004

Subject(s) - helicene , enantiopure drug , chirality (physics) , chemistry , reactivity (psychology) , stereochemistry , platinum , enantioselective synthesis , molecule , organic chemistry , catalysis , medicine , chiral symmetry breaking , physics , alternative medicine , pathology , quantum mechanics , quark , nambu–jona lasinio model

It was serendipitously observed that cis ‐[PtCl 2 (NCEt)PPh 3 ] reacted differently with either racemic or enantiopure 4‐aza[6]helicene, giving respectively cis (racemic) and trans (enantiopure) [Pt II Cl 2 (4‐aza[6]helicene)PPh 3 ] complexes. This unexpected reactivity is explained through a dynamic process (crystallization‐induced diastereoselective transformation) and enables a new aspect of reactivity in chiral transition‐metal complexes to be addressed.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research