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Gold‐Catalyzed Intermolecular CS Bond Formation: Efficient Synthesis of α‐Substituted Vinyl Sulfones
Author(s) -
Xi Yumeng,
Dong Boliang,
McClain Edward J.,
Wang Qiaoyi,
Gregg Tesia L.,
Akhmedov Novruz G.,
Petersen Jeffrey L.,
Shi Xiaodong
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201310142
Subject(s) - trifluoromethanesulfonate , chemistry , catalysis , combinatorial chemistry , sulfinic acid , intermolecular force , organic chemistry , molecule
A general method for the synthesis of α‐substituted vinyl sulfones makes use of a combination of a triazole gold complex and gallium triflate. This efficient CS bond formation between simple terminal alkynes and sulfinic acids provides access to various α‐substituted vinyl sulfones.