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Quantitative Photoswitching in Bis(dithiazole)ethene Enables Modulation of Light for Encoding Optical Signals
Author(s) -
Wu Yue,
Xie Yongshu,
Zhang Qiong,
Tian He,
Zhu Weihong,
Li Alexander D. Q.
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201309915
Subject(s) - light beam , modulation (music) , optoelectronics , optics , photochromism , visible spectrum , beam (structure) , materials science , chemistry , physics , nanotechnology , acoustics
Using one ray of light to encode another ray of light is highly desirable because information in optical format can be directly transferred from one beam to another without converting back to the electronic format. One key medium to accomplish such an amazing task is photoswitchable molecules. Using bis(dithiazole)ethene that can be photoswitched between its ring‐open and ring‐closed states quantitatively with excellent fatigue resistance and high thermal stability, it is shown that quantitative photoreversibility allowed the photoswitching light to control other light travelling through the photoswitchable medium, a phenomenon of transferring information encoded in one light ray to others, thus imparting photo‐optical modulation on the orthogonal light beam.