Frontiers in Rotational Spectroscopy: Shapes and Tunneling Dynamics of the Four Conformers of the Acrylic Acid—Difluoroacetic Acid Adduct | Zendy

Feng Gang | Zendy; Gou Qian | Zendy; Evangelisti Luca | Zendy; Caminati Walther | Zendy

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Frontiers in Rotational Spectroscopy: Shapes and Tunneling Dynamics of the Four Conformers of the Acrylic Acid—Difluoroacetic Acid Adduct

Author(s) -

Feng Gang,

Gou Qian,

Evangelisti Luca,

Caminati Walther

Publication year - 2014

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201308459

Subject(s) - conformational isomerism , adduct , acrylic acid , spectroscopy , chemistry , rotational spectroscopy , molecular dynamics , nuclear magnetic resonance spectroscopy , photochemistry , computational chemistry , stereochemistry , molecule , organic chemistry , physics , monomer , quantum mechanics , polymer

The rotational spectra of four conformers of the acrylic acid—difluoroacetic acid adduct (CH 2 =CHCOOH–CHF 2 COOH, AA‐DFA) are reported and information on their internal dynamics is supplied. This represents an unprecedented result for the conformational analysis, with microwave spectroscopy, of such a heavy molecular adduct.

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