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A Uranium‐Based UO 2 + –Mn 2+ Single‐Chain Magnet Assembled trough Cation–Cation Interactions
Author(s) -
Mougel Victor,
Chatelain Lucile,
Hermle Johannes,
Caciuffo Roberto,
Colineau Eric,
Tuna Floriana,
Magnani Nicola,
de Geyer Arnaud,
Pécaut Jacques,
Mazzanti Marinella
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201307366
Subject(s) - uranyl , chemistry , magnetization , crystallography , antiferromagnetism , uranium , pyridine , neutron diffraction , magnetic anisotropy , actinide , anisotropy , relaxation (psychology) , crystal structure , ion , inorganic chemistry , materials science , magnetic field , condensed matter physics , physics , social psychology , psychology , organic chemistry , quantum mechanics , medicinal chemistry , metallurgy
Single‐chain magnets (SCMs) are materials composed of magnetically isolated one‐dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide‐containing SCM. The 5f–3d heterometallic 1D chains [{[UO 2 (salen)(py)][M(py) 4 ](NO 3 )}] n , (M=Cd ( 1 ) and M=Mn ( 2 ); py=pyridine) are assembled trough cation–cation interaction from the reaction of the uranyl(V) complex [UO 2 (salen)py][Cp* 2 Co] (Cp*=pentamethylcyclopentadienyl) with Cd(NO 3 ) 2 or Mn(NO 3 ) 2 in pyridine. The infinite UMn chain displays a high relaxation barrier of 134±0.8 K (93±0.5 cm −1 ), probably as a result of strong intra‐chain magnetic interactions combined with the high Ising anisotropy of the uranyl(V) dioxo group. It also exhibits an open magnetic hysteresis loop at T <6 K, with an impressive coercive field of 3.4 T at 2 K.