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Preparation and Characterization of Alkenyl Aryl Tetrafluoro‐λ 6 ‐sulfanes
Author(s) -
Zhong Linbin,
Savoie Paul R.,
Filatov Alexander S.,
Welch John T.
Publication year - 2014
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201306507
Subject(s) - aryl , substituent , chemistry , reactivity (psychology) , fluorine , characterization (materials science) , group (periodic table) , medicinal chemistry , stereochemistry , combinatorial chemistry , organic chemistry , alkyl , nanotechnology , materials science , medicine , alternative medicine , pathology
Abstract Substituted alkenyl aryl tetrafluoro‐λ 6 ‐sulfanes have been prepared by the direct addition of readily accessible chlorotetrafluorosulfanyl arenes to primary alkynes. Substitution of an apical fluorine of the pentafluorosulfanyl group enables modulation of the reactivity of this little explored functional group while at the same time facilitating the direct investigation of aryl substituent effects on the aryl tetrafluorosulfanyl‐substituted products.