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Progress in Carbonylative [2+2+1] Cycloaddition: Utilization of a Nitrile Group as the π Component
Author(s) -
Iwata Takashi,
Inagaki Fuyuhiko,
Mukai Chisato
Publication year - 2013
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201305729
Subject(s) - nitrile , chemistry , cycloaddition , schema (genetic algorithms) , computer science , combinatorial chemistry , world wide web , medicinal chemistry , organic chemistry , information retrieval , catalysis
Neue Tricks in alten Reaktionen : 2‐(1,2‐Propadienyl)phenylacetonitrile werden in Gegenwart katalytischer Mengen [{RhCl(CO)dppp} 2 ] (dppp=1,3‐Bis(diphenylphosphanyl)propan) unter CO‐Atmosphäre in Benzo[ f ]oxyindole umgewandelt (siehe Schema). Diese Aza‐Pauson‐Khand‐Reaktion überführt aliphatische Substrate in Azabicyclo[3.3.0]octadienone.
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