Catalytic Enantioselective Synthesis of Tertiary Thiols From 5 H ‐Thiazol‐4‐ones and Nitroolefins: Bifunctional Ureidopeptide‐Based Brønsted Base Catalysis | Zendy

Diosdado Saioa | Zendy; Etxabe Julen | Zendy; Izquierdo Joseba | Zendy; Landa Aitor | Zendy; Mielgo Antonia | Zendy; Olaizola Iurre | Zendy; López Rosa | Zendy; Palomo Claudio | Zendy

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Catalytic Enantioselective Synthesis of Tertiary Thiols From 5 H ‐Thiazol‐4‐ones and Nitroolefins: Bifunctional Ureidopeptide‐Based Brønsted Base Catalysis

Author(s) -

Diosdado Saioa,

Etxabe Julen,

Izquierdo Joseba,

Landa Aitor,

Mielgo Antonia,

Olaizola Iurre,

López Rosa,

Palomo Claudio

Publication year - 2013

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201305644

Subject(s) - bifunctional , enantioselective synthesis , base (topology) , catalysis , chemistry , combinatorial chemistry , computer science , stereochemistry , organic chemistry , mathematics , mathematical analysis

Alles dran : Die difunktionelle Brønsted‐Base 1 mit Ureidopeptid‐Gerüst vermittelt die erste direkte katalytische Michael‐Reaktion von α‐Mercaptocarboxylat‐Surrogaten mit Nitroolefinen. Hierbei wird ein vollständig substituiertes Kohlenstoffzentrum in α‐Stellung aufgebaut.

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