Isolation of a Neutral P 8  Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus | Zendy

Dorsey Christopher L. | Zendy; Squires Brian M. | Zendy; Hudnall Todd W. | Zendy

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Isolation of a Neutral P 8 Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus

Author(s) -

Dorsey Christopher L.,

Squires Brian M.,

Hudnall Todd W.

Publication year - 2013

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201301137

Subject(s) - carbene , cycloaddition , cluster (spacecraft) , white phosphorus , phosphorus , service (business) , isolation (microbiology) , chemistry , computer science , library science , biology , organic chemistry , bioinformatics , programming language , catalysis , economy , economics

Paarbildung : Carbene mit Carbonylgruppen aktivieren weißen Phosphor sehr effektiv und liefern so carbenstabilisierte P 4 ‐ und P 8 ‐Cluster. Mechanistische Belege sprechen dafür, dass der P 8 ‐Cluster (siehe Röntgenbeugungsstruktur: C grau, P gelb, N blau, O rot) das Ergebnis der [2+2]‐Cycloaddition einer intermediären Diphosphenspezies ist.

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