Bio‐Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal‐Activated Substrate | Zendy

McSkimming Alex | Zendy; Bhadbhade Mohan M. | Zendy; Colbran Stephen B. | Zendy

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Bio‐Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal‐Activated Substrate

Author(s) -

McSkimming Alex,

Bhadbhade Mohan M.,

Colbran Stephen B.

Publication year - 2013

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201210086

Subject(s) - chemistry , imine , combinatorial chemistry , transfer hydrogenation , rhodium , hydride , substrate (aquarium) , catalysis , metal , organic chemistry , ruthenium , oceanography , geology

Ein Metallzentrum und ein organischer Hydriddonor sind in einem neuen Katalysator für die Transferhydrierung von Iminen mit Formiat unter Umgebungsbedingungen kombiniert. Ein Schlüsselschritt – der Hydridtransfer vom Donor auf das durch das Metall polarisierte Substrat – ähnelt einem entsprechenden Schritt bei Metallo(de)hydrogenase‐Enzymen.

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