Bimetallic Activation of 2‐Alkanones through Photo‐Induced α‐Hydrogen Abstraction Mediated by a Dinuclear Ruthenium Tetrahydride Complex | Zendy

Suzuki Hiroharu | Zendy; Shimogawa Ryuichi | Zendy; Muroi Yuki | Zendy; Takao Toshiro | Zendy; Oshima Masato | Zendy; Konishi Genichi | Zendy

Premium

Bimetallic Activation of 2‐Alkanones through Photo‐Induced α‐Hydrogen Abstraction Mediated by a Dinuclear Ruthenium Tetrahydride Complex

Author(s) -

Suzuki Hiroharu,

Shimogawa Ryuichi,

Muroi Yuki,

Takao Toshiro,

Oshima Masato,

Konishi Genichi

Publication year - 2013

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201208185

Subject(s) - ruthenium , chemistry , bimetallic strip , medicinal chemistry , photochemistry , hydrogen , hydrogen atom abstraction , catalysis , organic chemistry

Wasserstoff‐Abstraktion im Rampenlicht : UV‐Bestrahlung (365 nm) von zweikernigem Rutheniumtetrahydrid, [(Cp*Ru)(μ‐H) 4 (RuCp*)] (Cp*=η 5 ‐C 5 Me 5 ), in einem 2‐Alkanon wie Aceton oder 2‐Butanon führt zur Wasserstoff‐Abstraktion in den α‐ und α′‐Positionen zur Carbonylgruppe. Es entstehen zweikernige Oxatrimethylenmethan‐Komplexe, [(Cp*Ru)(μ‐η 3 :η 1 ‐CH 2 COCHR)(μ‐H) 2 (RuCp*)] (R=H und CH 3 ).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research