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[(μ‐C){Re(CO) 2 (η‐C 5 H 5 )} 2 ]: A Surprisingly Simple Bimetallic Carbido Complex
Author(s) -
Young Rowan D.,
Hill Anthony F.,
Cavigliasso Germán E.,
Stranger Robert
Publication year - 2013
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201207731
Subject(s) - bimetallic strip , chemistry , simple (philosophy) , x ray crystallography , crystallography , stereochemistry , physics , catalysis , diffraction , philosophy , organic chemistry , epistemology , optics
C‐Brücke : Die Reaktion von [Re(CO) 2 (CS)(η‐C 5 H 5 )] mit [Re(CO) 2 (thf)(η‐C 5 H 5 )] liefert den Dischwefelkomplex [Re(CO) 2 (η 2 ‐S 2 )(η‐C 5 H 5 )] und den bemerkenswert einfachen μ‐Carbidokomplex [(μ‐C){Re(CO) 2 (η‐C 5 H 5 )} 2 ], der strukturell charakterisiert und theoretisch untersucht wurde (siehe Bild; schwarz C, weiß H, rot O, grün Re).

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