Enantioselective Synthesis of Spiro Cyclopentane‐1,3′‐indoles and 2,3,4,9‐Tetrahydro‐1 H ‐carbazoles by Iridium‐Catalyzed Allylic Dearomatization and Stereospecific Migration | Zendy

Wu QingFeng | Zendy; Zheng Chao | Zendy; You ShuLi | Zendy

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Enantioselective Synthesis of Spiro Cyclopentane‐1,3′‐indoles and 2,3,4,9‐Tetrahydro‐1 H ‐carbazoles by Iridium‐Catalyzed Allylic Dearomatization and Stereospecific Migration

Author(s) -

Wu QingFeng,

Zheng Chao,

You ShuLi

Publication year - 2012

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201107677

Subject(s) - cyclopentane , enantioselective synthesis , stereospecificity , iridium , catalysis , allylic rearrangement , chemistry , stereochemistry , stereoisomerism , organic chemistry , combinatorial chemistry

Allyl greift an : Fünfgliedrige Spiroindolenine werden hoch enantioselektiv durch die iridiumkatalysierte intramolekulare allylierende Desaromatisierung von Indolen aufgebaut. Eine stereospezifische Umlagerung der resultierenden Spirocyclopentan‐1,3′‐indole ergibt enantiomerenangereicherte 2,3,4,9‐Tetrahydro‐1 H ‐carbazole.

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