Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry | Zendy

McLellan Ross | Zendy; Ellis David | Zendy; Rosair Georgina M. | Zendy; Welch Alan J. | Zendy

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Diphosphaborane and Metalladiphosphaborane: Ligands for Transition‐Metal Chemistry

Author(s) -

McLellan Ross,

Ellis David,

Rosair Georgina M.,

Welch Alan J.

Publication year - 2011

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201105820

Subject(s) - chemistry , transition metal , ligand (biochemistry) , stereochemistry , polymer science , organic chemistry , catalysis , biochemistry , receptor

Neue σ‐Liganden für Übergangsmetalle sind das neutrale Heteroboran [HCo(1,2‐ closo ‐P 2 B 10 H 10 ) 2 (PEt 3 ) 2 ] ( 1 , links) und das neutrale Metallaheteroboran μ‐[1,2‐{HRu( p ‐cymol)} 2 ‐7′,8′‐ nido ‐P 2 B 9 H 9 ]‐3‐( p ‐cymol)‐3,1,2‐ closo ‐RuP 2 B 9 H 9 ( 2 , rechts). In 1 koordiniert der P 2 B 10 H 10 ‐Ligand über ein P‐Atom an Co, und in 2 agieren der closo ‐RuP 2 B 9 ‐ und der nido ‐P 2 B 9 ‐Käfig als κP:κP′‐Brückenliganden.

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