Manganese‐Catalyzed Cleavage of a Carbon–Carbon Single Bond between Carbonyl Carbon and α‐Carbon Atoms of Ketones | Zendy

Kuninobu Yoichiro | Zendy; Uesugi Tadamasa | Zendy; Kawata Atsushi | Zendy; Takai Kazuhiko | Zendy

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Manganese‐Catalyzed Cleavage of a Carbon–Carbon Single Bond between Carbonyl Carbon and α‐Carbon Atoms of Ketones

Author(s) -

Kuninobu Yoichiro,

Uesugi Tadamasa,

Kawata Atsushi,

Takai Kazuhiko

Publication year - 2011

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201104704

Subject(s) - chemistry , carbodiimide , isocyanate , ketone , catalysis , amide , manganese , carbon fibers , cleavage (geology) , organic chemistry , medicinal chemistry , polymer chemistry , polyurethane , computer science , materials science , algorithm , composite material , fracture (geology) , composite number

C weg, N dran : Ketone werden durch Carbodiimide in Gegenwart katalytischer Mengen an [{HMn(CO) 4 } 3 ] oder [Mn 2 (CO) 10 ] in guten bis hervorragenden Ausbeuten in Amide umgewandelt. Dabei wird eine Kohlenstoff‐Kohlenstoff‐Einfachbindung des Ketons effizient gespalten. Alternativ zu den Carbodiimiden konnten auch Isocyanate eingesetzt werden.

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