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Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki–Miyaura Coupling Using High‐Molecular‐Weight, Helically Chiral Polyquinoxaline‐Based Phosphines
Author(s) -
Yamamoto Takeshi,
Akai Yuto,
Nagata Yuuya,
Suginome Michinori
Publication year - 2011
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201103792
Subject(s) - enantioselective synthesis , chemistry , combinatorial chemistry , stereochemistry , polymer chemistry , catalysis , organic chemistry
Katalytische Spirale : In Gegenwart helical‐chiraler Polychinoxalin‐basierter Phosphane (PQXphos) mit hohem Molekulargewicht gelingen hoch enantioselektive Suzuki‐Miyaura‐Kupplungen von 1‐Brom‐2‐naphthalinphosphonsäureestern mit o ‐Methylphenylboronsäuren.