Sr 3 [Co(CN) 3 ] and Ba 3 [Co(CN) 3 ]: Crystal Structure, Chemical Bonding, and Conceptional Considerations of Highly Reduced Metalates | Zendy

Höhn Peter | Zendy; Jach Franziska | Zendy; Karabiyik Barış | Zendy; Prots Yurii | Zendy; Agrestini Stefano | Zendy; Wagner Frank R. | Zendy; Ruck Michael | Zendy; Tjeng Liu Hao | Zendy; Kniep Rüdiger | Zendy

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Sr 3 [Co(CN) 3 ] and Ba 3 [Co(CN) 3 ]: Crystal Structure, Chemical Bonding, and Conceptional Considerations of Highly Reduced Metalates

Author(s) -

Höhn Peter,

Jach Franziska,

Karabiyik Barış,

Prots Yurii,

Agrestini Stefano,

Wagner Frank R.,

Ruck Michael,

Tjeng Liu Hao,

Kniep Rüdiger

Publication year - 2011

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201103717

Subject(s) - crystal structure , crystallography , trigonal crystal system , chemistry , chemical bond , x ray crystallography , rhodium , stereochemistry , physics , catalysis , diffraction , optics , organic chemistry

Überraschende Eigenschaften hält der trigonal‐planare Komplex [Co(CN) 3 ] 6− bereit (siehe Strukturbild; Co rot, C grau, N grün, Erdalkalimetall‐Gegenionen gelb). Bindungslängen und Ladungen der CN‐Liganden variieren, und das Co‐Zentrum verfügt über eine geschlossenschalige (d 10 ‐)Konfiguration.

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