Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent  N ‐Oxyl Radical | Zendy

Cardenas Allan Jay P. | Zendy; Culotta Brooks J. | Zendy; Warren Timothy H. | Zendy; Grimme Stefan | Zendy; Stute Annika | Zendy; Fröhlich Roland | Zendy; Kehr Gerald | Zendy; Erker Gerhard | Zendy

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Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N ‐Oxyl Radical

Author(s) -

Cardenas Allan Jay P.,

Culotta Brooks J.,

Warren Timothy H.,

Grimme Stefan,

Stute Annika,

Fröhlich Roland,

Kehr Gerald,

Erker Gerhard

Publication year - 2011

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201101622

Subject(s) - frustrated lewis pair , frustration , schema (genetic algorithms) , chemistry , stereochemistry , combinatorics , computer science , information retrieval , psychology , lewis acids and bases , organic chemistry , mathematics , social psychology , catalysis

Mit NO gegen Frustration : Das intramolekulare frustrierte Lewis‐Paar (FLP) Mes 2 PCH 2 CH 2 B(C 6 F 5 ) 2 fängt NO unter Bildung des neuartigen N ‐Oxylradikals P/B‐FLP‐NO . ab (siehe Schema). Nach der Koordination von NO an das FLP kann dieses H‐Atome aus Cyclohexen und Ethylbenzol abspalten, was zu P/B‐FLP‐NOH und der O‐funktionalisierten Spezies P/B‐FLP‐NOR führt.

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