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Facile Conversion of CO/H 2 into Methoxide at a Uranium(III) Center
Author(s) -
Frey Alistair S. P.,
Cloke F. Geoffrey N.,
Coles Martyn P.,
Maron Laurent,
Davin Thomas
Publication year - 2011
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201101509
Subject(s) - uranium , methoxide , chemistry , center (category theory) , catalysis , materials science , organic chemistry , crystallography , metallurgy
Hydrierung von CO : Die Reaktion von [U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)] in Toluol mit CO und H 2 unterhalb und unter Normalbedingungen liefert den Methoxid‐Komplex [U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)OMe].
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