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A Family of Heterometallic Cubane‐Type Clusters with an exo ‐Fe(CO) 3 Fragment Anchored to the Cubane
Author(s) -
Geetharani K.,
Bose Shubhankar Kumar,
Sahoo Satyanarayan,
Ghosh Sundargopal
Publication year - 2011
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201008101
Subject(s) - cubane , crystallography , chemistry , fragment (logic) , crystal structure , stereochemistry , computer science , programming language
Metallreiche Metallaborane : Eine exo ‐Fe(CO) 3 ‐Einheit an einem Cubangerüst ist charakteristisch für die Komplexe [(Cp*M) 2 (μ 3 ‐E) 2 B 2 H(μ‐H){Fe(CO) 2 } 2 Fe(CO) 3 ] (M=Mo, E=S, Se; M=Ru, E=CO; Cp*=η 5 ‐C 5 Me 5 ), die ersten Heterodimetall‐Cubancluster mit einer Borideinheit (siehe Struktur).

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