Tuning the Spin State of Cobalt in a Co–La Heterometallic Complex through Controllable Coordination Sphere of La | Zendy

Bao SongSong | Zendy; Liao Yi | Zendy; Su YanHui | Zendy; Liang Xu | Zendy; Hu FengChun | Zendy; Sun Zhihu | Zendy; Zheng LiMin | Zendy; Wei Shiqiang | Zendy; Alberto Roger | Zendy; Li YiZhi | Zendy; Ma Jing | Zendy

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Tuning the Spin State of Cobalt in a Co–La Heterometallic Complex through Controllable Coordination Sphere of La

Author(s) -

Bao SongSong,

Liao Yi,

Su YanHui,

Liang Xu,

Hu FengChun,

Sun Zhihu,

Zheng LiMin,

Wei Shiqiang,

Alberto Roger,

Li YiZhi,

Ma Jing

Publication year - 2011

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201007872

Subject(s) - cobalt , spin states , coordination sphere , spin (aerodynamics) , chemistry , crystallography , coordination complex , state (computer science) , moment (physics) , materials science , stereochemistry , physics , thermodynamics , inorganic chemistry , crystal structure , quantum mechanics , mathematics , metal , organic chemistry , algorithm

Die reversible Dehydratisierung von Komplex 1 schaltet den Spinzustand des Cobalts von Low‐Spin(LS)‐Co III zu High‐Spin(HS)‐Co II (siehe Bild). Dies ermöglicht es, das magnetische Moment von 0.48 μ B bei 120 °C auf 4.15 μ B bei 220 °C im vollständig dehydratisierten Komplex 1‐220 hochzufahren. notpH 6 =1,4,7‐Triazacyclononan‐1,4,7‐triyltris(methylenphosphonsäure).

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