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Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent
Author(s) -
Demir Selvan,
Mueller Thomas J.,
Ziller Joseph W.,
Evans William J.
Publication year - 2011
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201005898
Subject(s) - crystallography , tris , x ray crystallography , chemistry , group 2 organometallic chemistry , physics , molecule , diffraction , biochemistry , organic chemistry , optics
Überraschendes von einem Klassiker : Die Erforschung der (C 5 Me 4 H) − ‐Chemie von Sc‐, Y‐ und Lu‐Metallocenen führte zum ersten Bis(η 5 )‐(η 1 )‐koordinierten Tris(polyalkylcyclopentadienyl)‐Komplex und zu einer für Polyalkylcyclopentadienyle neuartigen Koordinationsweise über drei Atome (siehe Schema).

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