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Catalytic Asymmetric Bromoamination of Chalcones: Highly Efficient Synthesis of Chiral α‐Bromo‐β‐Amino Ketone Derivatives
Author(s) -
Cai Yunfei,
Liu Xiaohua,
Hui Yonghai,
Jiang Jun,
Wang Wentao,
Chen Weiliang,
Lin Lili,
Feng Xiaoming
Publication year - 2010
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201002355
Subject(s) - ketone , chemistry , catalysis , scandium , enantioselective synthesis , schema (genetic algorithms) , combinatorial chemistry , stereochemistry , organic chemistry , computer science , information retrieval
Sparsam mit dem Katalysator : In der unter milden Bedingungen über eine Bromonium‐Zwischenstufe verlaufenden Titelreaktion wurden mit 0.05 Mol‐% eines C 2 ‐symmetrischen N , N ′‐Dioxid‐Scandium(III)‐Komplexes hervorragende Resultate erzielt (siehe Schema).

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