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Rhodium‐Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands
Author(s) -
Wang ZhiQian,
Feng ChenGuo,
Zhang ShuSheng,
Xu MingHua,
Lin GuoQiang
Publication year - 2010
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201001883
Subject(s) - diene , conjugate , chemistry , bicyclic molecule , rhodium , catalysis , stereochemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , mathematics , mathematical analysis , natural rubber
Nichts geht über Diene : In der Titelreaktion mit anspruchsvollen Nitroalkenen ohne α‐Substituenten als Substraten und unter ArB(OH) 2 /KHF 2 ‐Bedingungen waren chirale Bicyclo[3.3.0]‐Diene die besten Liganden. Np = Naphthyl.
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