High‐Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System | Zendy

Takahashi Kohei | Zendy; Yamashita Makoto | Zendy; Ichihara Takeo | Zendy; Nakano Koji | Zendy; Nozaki Kyoko | Zendy

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High‐Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System

Author(s) -

Takahashi Kohei,

Yamashita Makoto,

Ichihara Takeo,

Nakano Koji,

Nozaki Kyoko

Publication year - 2010

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201001327

Subject(s) - hydroformylation , catalysis , olefin fiber , tandem , alcohol , terminal (telecommunication) , chemistry , rhodium , dual (grammatical number) , organic chemistry , combinatorial chemistry , materials science , computer science , composite material , art , telecommunications , literature

Beim Test dualer Katalysatorsysteme für die Tandemsequenz aus Hydroformylierung und Hydrierung zur einstufigen Herstellung von n ‐Undecanol aus 1‐Decen ergab die Kombination von Xantphos/[Rh(acac)(CO) 2 ] mit dem Shvo‐Katalysator 1 das beste Resultat (siehe Schema; acac=Acetylacetonat, DMA= N , N ‐Dimethylacetamid). Der Einsatz polarer Lösungsmittel verhindert die Bildung von Undecylformiat.

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