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Probing Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy
Author(s) -
Pavlik Jeffrey W.,
Barabanschikov Alexander,
Oliver Allen G.,
Alp E. Ercan,
Sturhahn Wolfgang,
Zhao Jiyong,
Sage J. Timothy,
Scheidt W. Robert
Publication year - 2010
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201000928
Subject(s) - anisotropy , nuclear magnetic resonance , spectroscopy , nuclear magnetic resonance spectroscopy , two dimensional infrared spectroscopy , resonance (particle physics) , chemistry , materials science , molecular physics , infrared spectroscopy , atomic physics , physics , optics , organic chemistry , quantum mechanics
Sondierung der Lage : Eine resonanzschwingungsspektroskopische Einkristallstudie lieferte detaillierte Informationen zu den In‐Plane‐Schwingungen eines Nitrosyl‐Eisenporphyrinats, [Fe(oep)(NO)] (siehe Bild; oep=Octaethylporphyrin). Der axiale Nitrosyl‐Ligand bestimmt die Richtung der In‐Plane‐Bewegung des Eisenzentrums.

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