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Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboroxines to β,β‐Disubstituted α,β‐Unsaturated Ketones
Author(s) -
Shintani Ryo,
Takeda Momotaro,
Nishimura Takahiro,
Hayashi Tamio
Publication year - 2010
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201000467
Subject(s) - rhodium , chemistry , catalysis , enantioselective synthesis , ketone , combinatorial chemistry , organic chemistry
Quartäre Kohlenstoffstereozentren werden durch die rhodiumkatalysierte 1,4‐Addition leicht zugänglicher Arylboronsäureanhydride an β,β‐disubstituierte α,β‐ungesättigte Ketone in Gegenwart eines chiralen Tetrafluorbenzobarrelen‐Liganden hoch enantioselektiv aufgebaut.

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