Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO 3  2−  as a Template Linker | Zendy

Yan Jun | Zendy; Long DeLiang | Zendy; Cronin Leroy | Zendy

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Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO 3 2− as a Template Linker

Author(s) -

Yan Jun,

Long DeLiang,

Cronin Leroy

Publication year - 2010

Publication title -

angewandte chemie

Language(s) - Slovenian

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201000076

Subject(s) - block (permutation group theory) , computer science , chemistry , nanotechnology , materials science , combinatorics , mathematics

Heteroatome kontrollieren den Aufbau nanoskaliger Heteropolyoxowolframate: Namentlich SeO 3 2− führte zur Bildung von [H 2 W 43 Se 3 O 148 ] 24− {W 43 Se 3 }, [H 4 W 77 Se 5 O 265 ] 44− {W 77 Se 5 }, [H 6 W 63 Se 6 O 221 ] 34− {W 63 Se 6 } und [H 8 W 100 Se 16 O 364 ] 56− {W 101 Se 16 }. Alle diese Clusteranionen leiten sich von einem gemeinsamen {W 22 Se 2 }‐Baustein ab und entstehen ohne Einsatz verbrückender Heterometallbausteine; die drei kleineren Cluster enthalten pentagonale W(W 4 )‐Einheiten.

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