Unusual  ipso  Substitution of Diaryliodonium Bromides Initiated by a Single‐Electron‐Transfer Oxidizing Process | Zendy

Dohi Toshifumi | Zendy; Ito Motoki | Zendy; Yamaoka Nobutaka | Zendy; Morimoto Koji | Zendy; Fujioka Hiromichi | Zendy; Kita Yasuyuki | Zendy

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Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single‐Electron‐Transfer Oxidizing Process

Author(s) -

Dohi Toshifumi,

Ito Motoki,

Yamaoka Nobutaka,

Morimoto Koji,

Fujioka Hiromichi,

Kita Yasuyuki

Publication year - 2010

Publication title -

angewandte chemie

Language(s) - German

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.200907281

Subject(s) - oxidizing agent , chemistry , substitution (logic) , substitution reaction , electron transfer , medicinal chemistry , polymer chemistry , combinatorial chemistry , photochemistry , organic chemistry , computer science , programming language

Iod kuppelt : Die Umsetzung der Diaryliodoniumbromide 1 mit aromatischen Nucleophilen 2 ergab eine Reihe von Heterobiarylen 3 in guten Ausbeuten. Diese ipso ‐Substitution am Heteroarenring von 1 verläuft über aromatische Radikalkationen, die durch Einelektronentransfer(SET)‐Oxidation von 2 erzeugt werden. HFIP=Hexafluor‐2‐propanol.

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