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Rhodium(I)‐Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes
Author(s) -
Inagaki Fuyuhiko,
Sugikubo Katsuya,
Miyashita Yusuke,
Mukai Chisato
Publication year - 2010
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200906994
Subject(s) - bicyclic molecule , rhodium , cycloaddition , intramolecular force , catalysis , chemistry , medicinal chemistry , stereochemistry , organic chemistry
Von Allenen zu Bicyclen : Bei der [{RhCl(CO) 2 } 2 ]‐ oder [{RhCl(CO)dppp} 2 ]‐katalysierten intramolekularen [5+2]‐Cycloaddition von Alkin‐Allenylcyclopropanen entstehen unter milden Bedingungen die Bicyclo[5.4.0]undecatrien‐ oder die größeren Bicyclo[5.5.0]dodecatrien‐Gerüste (dppp=1,3‐Bis(diphenylphosphanyl)propan).
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