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Copper‐Catalyzed Hydrosilylation with a Bowl‐Shaped Phosphane Ligand: Preferential Reduction of a Bulky Ketone in the Presence of an Aldehyde
Author(s) -
Fujihara Tetsuaki,
Semba Kazuhiko,
Terao Jun,
Tsuji Yasushi
Publication year - 2010
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200906348
Subject(s) - hydrosilylation , chemistry , aldehyde , ketone , catalysis , copper , ligand (biochemistry) , polymer chemistry , reduction (mathematics) , medicinal chemistry , organic chemistry , biochemistry , receptor , geometry , mathematics
Sperriges zuerst : Ein hoch aktiver Kupferkatalysator mit einem schalenförmigen Phosphanliganden (bsp) vermittelt eine bislang einzigartige Reaktion: die Hydrosilylierung von sperrigen Ketonen in Gegenwart eines ungeschützten Aldehyds.
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