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Olefin Cyclopropanation by a Sequential Atom‐Transfer Radical Addition and Dechlorination in the Presence of a Ruthenium Catalyst
Author(s) -
Thommes Katrin,
Kiefer Gregor,
Scopelliti Rosario,
Severin Kay
Publication year - 2009
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.200904278
Subject(s) - cyclopropanation , chemistry , cyclopropane , ruthenium , catalysis , diazo , olefin fiber , schema (genetic algorithms) , organic chemistry , information retrieval , computer science , ring (chemistry)
Ganz ohne Diazo: Die reduktive Kupplung von Olefinen mit Dichlorverbindungen in Gegenwart von Magnesium und einem Rutheniumkatalysator liefert in guter Ausbeute Cyclopropane (siehe Schema).